Honestly I'm interested in Mathilde reading a book about True Dhar and see what kind of lore Boney writes for it. Also love the idea of Mathilde just understanding Dhar better without ever touching it.
Ulgu would be best for us, but at the same time if they have something useful for us the cost would most likely be extremely high, for a book about True Dhar 101 for beginners probably not so much (also far less unlikely they bobby trap stuff on the level of apprentices).
Though as I said not clue what we could give them for it that we're willing to give them for it. AV is a no go for me like, I can already imagine Druchii sorceresses using it to make something horrible, like maybe they end up creating a MORBs of pure Dhar (which sounds terrifying tbh)
Information on Ulgu would be used to better cast Ulgu yes, but info on True Dhar would be useful to better dispel and otherwise counter True Dhar, of which the Druchi are practically the only users on the planet, give or take a few crazier than usual Asrai. She would probably be even more disinclined to give us that
A Orb of Dhar is called a spherical chunk of warpstone and you can get those by less exotic means, say digging them out of the ground.