I suspect that Lord of Arrows will be limited by how fast she can think. She can't carefully select the perfect target for a million shots because there are too many going by and they're too fast to think for each one. Picking one target for all the shots would work though. An attack at sufficient velocity (hehehe) would be too fast for her to pick a target however. So she works best in small engagement with slow/small amount of shots, like arrows which would fit for an ability like Lord of Arrows.
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