Sure they could. They could torture Lex Luthor to death. At this point, even with him helping them, he's proven far more of a liability to the species than a boon to it.
A Light board member is the current ruler of Hell.Ophidi-Scan could locate every one of the Light, and from there it's less than a moment to throw all of them bar Klarion into the sun. Klarion should be sorted first, but the rest can be executed straight after.
You kill them and all you manage is to make Saturnus more powerful vis a vis the rest of the Light.
I do suspect that it's about to become a pressing foreign policy objective for OL/the League to arrange for the freedom of several of the other Lords of Hell.
Saturnus only gets to pull this shit because he isn't currently worrying about the other Demon Princes pulling their own power plays in Hell.
Freeing them would drastically cut down on the attention he can spare for foreign adventures, and it would also make the Light's staging grounds in hell much less secure.
She doesn't like to think about that.