[X] A stoic woman
Could be Nanao, could be Nemu. Rangiku is probably not "stoic", sadly.
Blustering man might be Omaeda, but it could also be Captain Wolf Head's lieutenant. Whose name escapes me. He wears sunglasses, and has drinking contests with Ikkaku.
Edit: Also, the whole fight with Zangetsu went pretty well, I'd say. Got some good talk time in, landed some shots. Good update, definite progress.