I wouldn't say they're that ambivalent before that. That the CS went around and butchered innocent D-Bees, mages, and you're pretty much expected to fight against them was fairly clear. There were iirc some direct comparisons to Nazis even in-universe too.
I'd say almost the opposite- over time the Coalition States has been shown to overlook harmless DBs more (even while still retaining the right to kill them for no reason), and the demon invasion storyline allowed them to be in the relatively-heroic side.
5ed is I think the *most* explicit about this compared to other editions, contrary to what one might expect. I will say 'ceasing to be a devil' is quite possible.
Pathfinder is more in line with other editions, and one of the big adventure path has a redeemed demon as one of your big allies- and it mentions for an after-game bonus that converting possibly the most powerful of the Demon Lords is a possible way for the game to go! I mean, best-case scenario there is her becoming a chaotic neutral goddess of assassinations, but hey, victory is a victory. Also, they really gotta include some redeemed demons that aren't ex-succubi at one point... I can see the appeal and 'interacts with mortals the most' is even a not bad Watsonian explanation, but still!
Eberron is also explicit that nothing is "Always X". Even the mind-possessing outsider entities have defectors, and any mortal one even more-so, and even beings of an alignment won't always be that way on everything. One of the kingdoms of lead by an evil vampire... who honestly seeks lasting peace for his country for good reasons.